Summary of Theory
2005 Summary written by Antonella De Ninno (Source)
The decision of Martin Fleischmann to embark in 1983 on Cold Fusion research was based on the belief that Quantum Mechanics alone was not able to explain some experimental facts, which require some new approach.
The Fleischmann intuition implied that nuclear transformations of D+ compressed into Pd lattice would differ substantially from the reactions observed in dilute plasmas.
The question about the reality of CF is usually asked in the context of Quantum Mechanics which shows that “Cold Fusion” should not be possible:
the nuclear physics of deuterons in the lattice (with a spacetime scale some six orders of magnitude smaller than the spacetime scales of the lattice) should not differ from the nuclear physics in the vacuum (that is the principle of Asymptotic Freedom).
However Asymptotic Freedom is not a general property of the coherent ground state of QED in condensed matter!
QED is the relativistic quantum field describing interaction of electrically charged particles via photons and it is therefore a good candidate to describe the interactions among particles and fields inside condensed matter.
In 1989 Emilio Del Giudice together with Giuliano Preparata and Tullio Bressani investigated the system in the context of QED. The ground state in condensed matter involves the atoms/molecules of a macroscopic piece of matter in an intricate dynamical interplay mediated by large amplitude (classical) e.m. field. In such a scenario the Asymptotic Freedom is not a general property of such a coherent ground state because the e.m field fills the vacuum among the particles inside the matter and interacts strongly with the charges.
This intuition was substantially shared by Julian Swinger, one of the fathers of QED.
Suppose that a fusion be a physical event localized at a definite site of the lattice. The compound nucleus D+D must release its exceeding energy (in order to relax to a stationary state) in the time allowed by the Heisenberg uncertainty principle DEDt ~ ħ. In order to reach the nearest atom at a distance of about 3 Å (i.e. about the distance between first neighbour in Pd lattice) the velocity of the energy transfer should be orders of magnitudes larger than the light speed, then the only possibility for the nucleus is to fission in fragments as expected in vacuum!
Even if we are able to find in condensed matter quantum electrodynamic a mechanism able to justify weak interactions such as the capture of “heavy” electrons by proton as suggested recently by Larsen and Widom it is still hard to imagine a mechanism able to dissipate the energy produced locally different from a coherent electromagnetic field.
According to the universally accepted principle of physics it is impossible to dissipate energies of MeV simply “heating” the lattice without emission of very energetic fragments that have not been observed in these phenomena.
Cold fusion cannot be a localized event but implies the revision of some of our implicitly assumed facts about condensed matter.
1993 Summary written by Peter Hagelstein
Preparata has been working on theory for coherent ddfusion reactions; a major goal of the theory is to account for the heat production by a modified ddfusion reaction where the 4He branch dominates, and the gamma emission is replaced by energy transfer with the lattice. He argues that a proper quantization of the low energy electromagnetic field coupled to the metal electrons leads to enhanced screening between deuterons. He then proposes that the 4He branch is favored by coherence factors that come about when the reaction energy (24 MeV) is transferred to the lattice.
In some sense, this is a version of the “classical” cold fusion model, which would be essentially forced somehow to be true if Fleischmann's initial conjecture that the effect was due to fusion were accepted. I consider this general type of model to be essentially the only game in town if it is assumed (following Fleischmann's initial conjecture) that the reaction mechanism must be fusion. I spent 6 months working on it myself in 1989
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